Adjectival Phrase
الصَّلَوَاتُ الْخَمْسُ
Meaning 
The five prayers
الصَّلَوَاتُ
this word means prayers. It is plural
الْخَمْسُ
this word means five 
Together they form an adjectival phrase.
Note that in an adjectival phrase both words have Alif Laam at the beginning. This is because the noun must agree with its adjective in definiteness. If the noun has Alif Laam so must the adjective. If the noun does not have Alif Laam, then the adjective cannot have Alif Laam.
Also note that they both have dammah on the last letter. The adjective and noun must agree with one another in state. A word which has dammah on the last letter is said to be in the nominative case. The adjective has to be in the nominative case if the noun is in the nominative case.
If the noun is in the genitive case so must the adjective, and if the noun is in the accusative case so must the adjective.  
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